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971.
Almost half (354) of all fish kills (805) in South Carolina, USA, between 1978 and 1988 occurred in the coastal zone. These
kills were analyzed for causative, spatial, and temporal associations as a distinct data set and as one integrated with ambient
water quality monitoring data. Estuarine kills as a result of natural causes accounted for 42.8% followed by man-induced (35.1%)
and undetermined causes (22.1%).
Although general pesticide usage was responsible for 53.9% of man-induced kills, weed control activities around resorts and
municipal areas accounted for slightly more kills (20.9%) than did agricultural (19.8%) or vector control (13.2%) uses. A
dramatic decline in agricultural-related kills has been observed since 1986 as the integrated pest management approach was
adopted by many farmers. When taken with the few kills (12.0%) resulting from wastewaters, this suggests that these two land-use
activities have been successfully managed via existing programs (IPM and NPDES, respectively) to minimize their contributions
to estuarine fish kills.
Ambient trend monitoring data demonstrated no coastal-wide dispersion of pesticide pollution. These data confirmed the nature
of fish kills to be site-specific, near-field events most closely associated with the contiguous land-use practices and intensities.
Typically, fish kill data are considered as event-specific data limited to the bounds of that event only. Our analysis has
shown, however, that a long-term data set, when integrated with ambient water quality data, can assist in regulatory and resource
management decisions for both short- and long-term planning and protection applications. 相似文献
972.
973.
ABSTRACT: A linear filter (Kalman filter) technique was used with a Streamflow-concentration model the minimize surface water quality sampling frequencies when determining annual mean solute concentrations with a predetermined allowable error. The Kalman filter technique used the stream discharge interval as a replacement for the more commonly used time interval. Using filter computations, the measurement error variance was minimized within the sample size constraints. The Kalman filter application proposed here is applicable only under several conditions including: monitoring is solely to estimate annual mean concentration; discharge measurement errors are negligible; the Streamflow-concentration model is valid; and monthly samples reflect the total variance of the solute in question. 相似文献
974.
Amleto A. Pucci Douglas A. Harriman Elisabeth M. Ervin Lisa Bratton Alison Gordon 《Journal of the American Water Resources Association》1989,25(6):1267-1272
ABSTRACT: The U.S. Geological Survey collected ground-water samples from the upper and middle aquifers of the Potomac-Raritan-Magothy aquifer system in a 400-square-mile area of New Jersey from 1984 through 1986. Concentrations of lead were greater than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 50 micrograms per liter in water from 16 of 239 wells. The cencentrations of cadmium were greater than the MCL of 10 micrograms per liter in water from 10 to 241 wells. One-half of the wells that exceeded the lead MCL were in known areas of saltwater intrusion, as were all 10 wells that exceeded the cadmium MCL. The association of elevated concentrations of these metals with elevated concentrations of chloride indicates a mochanism related to saltwater intrusion. 相似文献
975.
ABSTRACT: A finite element model based on Galerkin's upstream weighted residual technique was developed to predict the simultaneous convective-dispersion transport and transformations of pesticides and their metabolites in the unsaturated zone. Transformations of the parent compound and its metabolites were assumed to be first-order reactions for oxidation and hydrolysis, while adsorption of the pesticide species (parent compound and metabolites) to the soil components was assumed to be represented by a linear equilibrium (Freundlich type) isotherm. Volatilization and plant root uptake of pesticides in the solution phase were neglected in the analysis. The proposed model was used to simulate the transport and transformation of aldicarb and its metabolites, aldicarb sulfoxide and aldicarb sulfone, in the soil profile. Several examples are used to demonstrate the accuracy, validity, and applicability of the proposed model. Simulated results indicate that the proposed model can potentially be used to estimate the mass flux of water, and pesticide and pesticide metabolite concentrations in the subsurface environment. However, further verification of the model against actual field data is needed to fully demonstrate the model's potential. 相似文献
976.
Marc O. Ribaudo C. Edwin Young 《Journal of the American Water Resources Association》1989,25(1):71-78
ABSTRACT: A framework for estimating the water quality benefits from soil erosion was developed. The framework is based on the linkages between soil erosion and offsite damages. The linkages are: erosion on the field, movement of eroded materials to waterways, impact of discharged material on water quality parameters, impact of water quality changes on ability of water to provide economic services, and the economic value of the changes in water use. These linkages need to be modeled in order to estimate the water quality benefits from reductions in soil erosion. Methods for modeling each link on a geographic level, which enables the analyses of national soil conservation, were examined. Areas where data or models were found to be lacking include transport of sediment and nutrients to water systems, impact of discharged materials on water quality parameters, and impact of water quality on ability of water to provide economic services. An economic evaluation of 1983 soil conservation programs was presented as an example of how the framework could be used. A number of simplifying assumptions were made to represent links that could not be modeled with available data. 相似文献
977.
978.
Gregory M. Clark Robert S. Williams 《Journal of the American Water Resources Association》1991,27(1):93-100
ABSTRACT: Batch-mixing experiments were used to help identify lithologic and mineralogic sources of increased concentrations of dissolved solids in water affected by surface coal mining in northwestern Colorado. Ten overburden core samples were analyzed for mineral composition and mixed with distilled water for 90 days until mineral-water equilibrium was reached. Between one day and 90 days after initial contact, specific conductance in the sample mixtures had a median increase of 306 percent. Dissolved-solids concentrations ranged from 200 to 8,700 mg/L in water samples extracted from the mixtures after 90 days. Mass. balance simulations were conducted using the geochemical models BALANCE and WATEQF to quantify mineral-water interactions occurring in five selected sample mixtures and in water collected from a spring at a reclaimed mine site. The spring water is affected by mineral-water interactions occurring in all of the lithologic units comprising the overburden. Results of the simulations indicate that oxidation of pyrite, dissolution of dolomite, gypsum, and epsomite, and cation-exchange reactions are the primary mineral-water interactions occurring in the overburden. Three lithologic units in the overburden (a coal, a sandstone, and a shale) probably contribute most of the dissolved solids to the spring water. Water sample extracts from mixtures using core from these three units accounted for 85 percent of the total dissolved solids in the 10 sample extracts. Other lithologic units in the overburden probably contribute smaller quantities of dissolved solids to the spring water. 相似文献
979.
Jiri Marsalek 《Journal of the American Water Resources Association》1991,27(2):283-291
ABSTRACT: A review of methods for planning-level estimates of pollutant loads in urban stormwater focuses on transfer of charac. teristic runoff quality data to unmonitored sites, runoff monitoring, and simulation models. Load estimation by transfer of runoff quality data is the least expensive, but the accuracy of estimates is unknown. Runoff monitoring methods provide best estimates of existing loads, but cannot be used to predict load changes resulting from runoff controls, or other changes of the urban system. Simulation models require extensive calibration for reliable application. Models with optional formulations of pollutant build up, washoff, and transport can be better calibrated and the selection of options should be based on a statistical analysis of calibration data. Calibrated simulation models can be used for evaluation of control alternatives. 相似文献
980.
Heinz G. Stefan .Ruochuan Gu 《Journal of the American Water Resources Association》1991,27(6):967-978
ABSTRACT: Forced artificial mixing of temperature-stratified ponds, or small lakes or reservoirs, by liquid jets can enhance water quality and can also be energy efficient. Based on previous studies of jet mixing mechanics of stratified water bodies, a conceptual design approach is presented. The main “operational” and “system” design parameters are considered in the proposed method. Using minimization of a total cost estimate as a criterion, an iterative method for the selection of the number and size of the jets is developed and illustrated. 相似文献